Chemistry Reference
In-Depth Information
Fig. 15 (a, b) The Au
20
kernel structure in Au
28
(SPh
-t-
Bu)
20
;(c, d) models of cuboctahedron and
interpenetrated bicuboctahedron [
12
]
Fig. 16 Thiolate-binding modes in Au
28
(SPh-
t
-Bu)
20
:(a) dimeric staples (total: four); (b) bridg-
ing thiolates (total: eight); (c) overall Au
28
S
20
framework. (Color labels:
magenta ¼
Au atoms in
the kernel,
blue ¼
Au in dimeric staples,
yellow ¼
sulfur, the four dimeric staples are highlighted
in
green
in panels a and c)