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Figure 7.3
(Top le
) The Chugaev reaction. (Top right) Related decomposition of cadmium ethylxanthate: (A) nucleophilic attack on
thiocarbonyl centre by triethylamine; (B) protonated intermediates; (C) triethylamine stabilisation of the metal centre.
Reprinted with permission from N. Pradhan, B. Katz and S. Efrima,
J. Phys. Chem. B
, 2003, 107, 13843. Copyright 2003
American Chemical Society.
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