Chemistry Reference
In-Depth Information
The bondon is the quantum particle corresponding to the superimposed electronic
pairing effects or distribution in chemical bond; accordingly, through the values of
its mass and velocity it may be possible to indicate the type of bonding (in particular)
and the characterization of electronic behavior in bonding (in general).
However, one of the most important consequences of bondonic existence is that
the chemical bonding may be described in a more complex manner than relaying
only on the electrons, but eventually employing the fermionic (electronic)-bosonic
(bondonic) mixture: the first preeminent application is currently on progress, that is,
exploring the effect that the Bose-Einstein condensation has on chemical bonding
modeling (Putz
2011a
,
b
;
2012a
,
b
,
c
,
d
). Yet, such possibility arises due to the fact
that whether the Pauli principle is an independent axiom of quantum mechanics or
whether it depends on other quantum description of matter is still under question
(Kaplan
2002
), as is the actual case of involving hidden variables and the entangle-
ment or non-localization phenomenology that may be eventually mapped onto the
delocalization and fractional charge provided by quantum chemistry over and on
atomic centers of a molecular complex/chemical bond, respectively.
On the other side, the mass, velocity, charge, and life-time properties of the
bondons may be employed for analyzing some typical chemical bonds, with the
respective working formulae as following.
The bondonic mass, having the quantization form
h
2
2
1)
2
E
bond
X
bond
(2
πn
+
m
B
=
¯
,
n
=
0,1, 2
...
(12.1)
is more practical than the traditional characterization of bonding types in terms of
length and energy of bonding; it may further assume the numerical ground state ratio
form
m
B
m
0
=
87
.
8603
(
E
bond
[
kcal/mol
])
X
bond
[
ς
m
=
(12.2)
A
]
2
0
when the available bonding energy and length are considered (as is the custom for
chemical information) in kcal/mol and Angstrom, respectively. Note that having the
bondon's mass in terms of bond energy implies the inclusion of the electronic pairing
effect in the bondonic existence, without the constraint that the bonding pair may
accumulate in the internuclear region (Berlin
1951
).
Moreover, since the bondonic mass general formulation (12.1) resulted within the
relativistic treatment of electron, it is considering also the companion velocity of the
bondonic mass that is reached in propagating the bonding information between the
bonding attractors. As such, when the Einstein type relationship (Einstein
1905a
)
mv
2
2
=
hυ
(12.3)
is employed for the relativistic bondonic velocity-mass relationship (Einstein
1905b
,
c
)
m
B
1
m
=
(12.4)
v
2
c
2
−
