Environmental Engineering Reference
In-Depth Information
Rearranging,
α
x
y
=
applies to any stage.
1
+
x (
α
1)
Substituting into the overall mass balance:
α
x n 1
L
V x n +
D
V
1) =
x D ;
D
=
V
L ;
1
+
x n 1 (
α
L
V =
L
V =
D
V =
1
1
R V
=
R V x n +
(1
R V )x D ;
R V
=
internal reflux ratio.
x n x n 1 +
ax n +
bx n 1 +
C
=
0 (Ricatti difference equation);
1
α
(
α
1) x D (1
R V )
α
x D (1
R V )
a
1 ;
b
;
c
1) .
R V (
α
1)
R V (
α
Substitution: let x n =
h (this is a coordinate transformation which shifts the system
to the intersection of the operating and equilibrium lines):
z n +
( z n +
h )( z n 1 +
h )
+
a ( z n +
h )
+
b ( z n 1 +
h )
+
c
=
0
h 2
z n z n 1 +
z n ( a
+
h )
+
z n 1 ( b
+
h )
+
+
h ( a
+
b )
+
c
=
0
set
=
0
4 c
( a
1
2
b ) 2
h
=
( a
+
b )
±
+
becomes defining equation for h
.
Now divide by z n z n 1 :
1
z n 1
1
z n
1
+
( a
+
h )
+
( b
+
h )
=
0
.
1
z n
Let v n =
v n ( b
+
h )
+
v n 1 ( a
+
h )
=−
1
v ( h )
n
n
=
c
β
n ( b
n 1 ( a
β
+
h )
+ β
+
h )
=
0
a
+
h
β =−
b
+
h
1
v ( P )
n
=−
a
+
b
+
2 h
C 1
n
a
+
h
1
1
z n =
1
x n
v n =
2 h =
h .
b
+
h
a
+
b
+
Rearrange and substitute to get the equation for x n :
1
x n =
h
+
C 1
n
.
a
+
h
1
b
+
h
a
+
b
+
2 h
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