Environmental Engineering Reference
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where i L [ ω ] is the thermal current spectral function of the left
thermal lead:
Tr A [ ω ] L [ ω ] G < [ ω ] L [ ω ] .
i ω
2 π
i L [ ω ] =
(3.56)
Similarly, the thermal current spectral function of the right
thermal lead is
Tr A [
R [ ω ] G < [ ω ] R [ ω ] .
i ω
2 π
i R [ ω ] =
ω
]
(3.57)
The two thermal leads always give same total current for
steady states. However, their spectral functions can be different if
asymmetry exists. A thorough investigation of thermal rectification
requires suchinformation.
3.2.4 Thermal Conductance and Phonon Transmission
Thermal conductance is defined as
I
T ,
σ = lim
(3.58)
T
0
where T is the temperature difference between the two thermal
leads, assuming that the temperature of the left and right thermal
leads are T + T / 2and T T / 2, respectively. We introduce
variationalderivative forGreen's function as
δ G
δ T = lim
F ( T L , T R ) F ( T , T )
T L T R
T 0
+
/
/
F ( T
T
2, T
T
2)
F ( T , T )
=
lim
(3.59)
T
T
0
Similar variational derivative is introduced for other functions,
like self energy and thermal current. As variational derivative of
thermal current with respect to temperature, thermal conductance
can beexpressed as
ω
2
π ω
d
f
˜
σ =
ω
(
),
(3.60)
T
0
where ˜
( ω ) is the effectivephonon transmission function.
The effectivephonon transmission of the left thermal lead is
L ( ω ) = Tr G r ( R +
L ,
1
˜
2 n + S ) G a
(3.61)
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