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Note that Kramers' theory affords insight into how to express the pre-factor R , which in
the case of the double-well potential can be shown to be the product of the potential fre-
quency at the bottom of the well and that at the top of the barrier divided by the friction
is determined by
the Einstein relation to be the thermodynamic temperature k B T . Of course, this is only
the case in discussing a physical web and is not true in general, as we shall show. Here
we expand the perturbation piece of the exponential and replace ( 7.86 ) with
. The diffusion coefficient D divided by the dissipation parameter
g ± (
) =
g 0 (
ε
)),
t
1
cos
t
(7.87)
where we limit ourselves to stressing that
ε
1,
Q 0
D ka
ε =
,
(7.88)
and the unperturbed coupling parameter is
R exp
Q 0
D
g 0 =
.
(7.89)
We are naturally led to replace ( 7.60 ) with
d
dt p
(
) =
(
)
(
),
t
g 0 K
t
p
t
(7.90)
where the time-dependent matrix K
(
t
)
now has the form
−[
1
ε
cos
t
) ] /
2
+[
1
+ ε
cos
t
) ] /
2
K
(
t
) =
.
(7.91)
+[
1
ε
cos
t
) ] /
2
−[
1
+ ε
cos
t
) ] /
2
Using the perturbed form of the coupling matrix ( 7.91 )in( 7.90 ) yields the equation of
motion for the difference variable
d
dt (
t
) =−
g 0 (
t
) +
g 0 ε
cos
t
),
(7.92)
where p 1 +
p 2 =
1 is used in the second term. The exact solution to this equation is
g 0 t
0
(
t
) =
exp
(
g 0 t
)(
0
) + ε
ds exp
(
g 0 (
t
s
))
cos
s
).
(7.93)
Let us assume that initially the web is in equilibrium so the probability of being in
either of the wells is the same and consequently
(
0
) =
0. We define the variable
ξ s (
t
)
,
which has the value 1 when the network S is in the right well and the value
1 when
the network S is in the left well. Thus, we write for the average web response ( 7.93 )in
the familiar LRT form
t
0 χ(
t p (
t )
dt ,
ξ s (
) = ε
t
t
,
(7.94)
where the response function is
t ) =
t ) ]
χ(
t
,
g 0 exp
[−
g 0 (
t
(7.95)
 
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