Polychlorotriphenylmethyl Radicals: Towards Multifunctional Molecular Materials - Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds - page 41

16 µ A

0.5 0.0 − 0.5 − 1.0 Volts

10 −4 M) in CH 2 Cl 2 using 0,1M Bu 4 N + PF 6 −

Figure 2.4 Cyclic voltammogram of triradical 3 (3 · as electrolyte

(vsSCE).(Reprintedwithpermissionfrom[18b].Copyright1993AmericanChemicalSociety.)

10mT 10mT

169.2 mT

169.2 mT

X 40 X 25

338.5 mT 338.5 mT

X 40

X 25

Figure2.5 Top:ExperimentalEPRfirstderivativespectraat143Kinglassytolueneofpuresamplesof(left) C 2 -3
( 3a quartet) and (right) D 3 -3 ( 3b quartet).Bottom: Simulated spectra for randomly oriented species. Insets show
the observed and simulated signals corresponding to

2 forbidden transitions of quartets. (Reprinted
withpermissionfrom[18b].Copyright1993AmericanChemicalSociety.)

M s =±