Chemistry Reference
In-Depth Information
see: a) S. Kobatake, S. Takami, H. Muto,
et al
.,
Nature
,
446
, 778 - 781 (2007); b) V. Balzani, A. Credi,
and M. Venturi, Memories, Logic Gates, and Related Systems, in
Molecular Devices and Machines
2nd Edn,
Wiley-VCH Verlag GmbH, Weinheim, 2008; c) B. L. Feringa (Ed.),
Molecular Switches
2nd Edn, Vol 1 - 2
Wiley-VCH Verlag GmbH, Weinheim, 2008.
42.
K. Hatanaka, Y. Morita, T. Ohba,
et al
.,
Tetrahedron Lett
.,
37
, 877 -880 (1996).
43.
Y. Morita, T. Ohba, N. Haneda,
et al
.,
J. Am. Chem. Soc
.,
122
, 4825 -4826 (2000).
44.
Y. Morita, S. Maki, K. Fukui,
et al
.,
Org. Lett
.,
3
, 3099 -3102 (2001).
45.
Y. Morita, J. Kawai, S. Nishida,
et al
.,
Synth. Met
.,
137
, 1217 -1218 (2003).
46.
T. Mochida, A. Izuoka, T. Sugawara,
et al
.,
J. Chem. Phys
.,
101
, 7971 -7974 (1994).
47.
Y. Morita, S. Suzuki, unpublished result.
48.
Y. Morita, S. Suzuki, J. Kawai,
et al
.,
Synth. Met
.,
137
, 1209 -1210 (2003).
49.
Galvinoxyl is an interesting neutral radical having a possibility for showing the “redox-based spin diversity”
nature. However, low stability of the radical dianion species may hamper its realization, see: a) A. I. Prokof'ev,
S. P. Solodovnikov, G. A. Nikiforov, and V. V. Ershov,
Izv. Akad. Nauk SSSR, Ser. Khim
., 324 -328 (1971);
b) S. G. Kukes, N. N. Bubnov, A. I. Prokof'ev,
et al
.,
Izv. Akad. Nauk SSSR, Ser. Khim
., 2375 - 2378 (1973).
50.
a) Y. Morita, T. Okafuji, and M. Satoh, Jpn. Kokai Tokkyo Koho JP 2007227186 A 20070906, 2007;
b) S. Nishida, Y. Morita, M. Moriguchi,
et al
., Molecular crystalline secondary batteries: properties of
phenalenyl-based multi-stage redox systems as cathode active organic materials. Presented at the 1st
Russian-Japanese Workshop “Open Shell Compounds and Molecular Spin Devices”, Novosibirsk, Russia, June
30 - July 2, 2007.
51.
Preliminary results on molecular crystalline secondary batteries based on closed-shell electron-donor and
-acceptor molecules as cathode-active materials are reported. Y. Morita, S. Nishida, N. Akutagawa,
et al
., Molec-
ular crystalline secondary batteries: novel secondary batteries based on organic molecules as cathode-active
materials. Presented at the 19th Symposium on Fundamental Organic Chemistry, Osaka, Japan, October 3 - 5,
C28, 2008.
52.
a) Y. Morita, J. Kawai, N. Haneda,
et al
.,
Tetrahedron Lett
.,
42
, 7991 -7995 (2001); b) S. Nishida, Y. Morita,
K. Fukui,
et al
.,
Angew. Chem. Int. Ed
.,
44
, 7277 - 7280 (2005).
53.
If one oxidation state from the TTF moiety is realized, relatively strong intramolecular spin interactions between
the
6OPO
neutral radical and the donor radical cation due to a spin polarization effect through the
π
-electron
network can be expected. See: Ref. 52a.
54.
An intra- and inter-molecular spin-site exchange natures depending on temperature are realized in metal com-
plexes having ferrocene and metallofullerene moieties. In these systems, high redox abilities of metal complex
moieties play vital roles. See: a) I. Ratera, D. Ruiz-Molina, F. Renz,
et al
.,
J. Am. Chem. Soc
.,
125
, 1462 -1463
(2003); b) C. Sporer, I. Ratera, D. Ruiz-Molina,
et al
.,
Solid State Sci
.,
11
, 786 - 792, (2009); c) T. Tsuchiya,
K.Sato,H.Kurihara,
et al
.,
J. Am. Chem. Soc
.,
128
, 14418 -14419 (2006).
55.
Photo-induced valence tautomerism based on transition metal complexes, see: a) D. M. Adams, B. Li,
J. D. Simon, and D. N. Hendrickson,
Angew. Chem. Int. Ed
.,
34
, 1481 - 1483 (1995); b) O, Sato, J. Tao, and
Y.-Z. Zhang,
Angew. Chem. Int. Ed
.,
46
, 2152 - 2187 (2007); c) O, Sato, A. Cui, R. Matsuda,
et al
.,
Acc.
Chem. Res
.,
40
, 361 - 369 (2007), and references therein.
56.
“Photo-induced spin-center transfer” in purely organic open-shell system is recently achieved in the
6OPO
derivative. Y. Morita, S. Nishida, unpublished result.
57.
a) I. C. Paul, and G. A. Sim,
Proc. Chem. Soc
., 352 -353 (1962); b) R. Aderjan, H. Breer, H. J. Keller, and
H. H. Rupp,
Z. Naturforsch
.,
28B
, 164 - 167 (1973); c) Y. Demura, T. Kawato, H. Kanatomi, and I. Murase,
Bull. Chem. Soc. Jpn
.,
48
, 2820 - 2824 (1975); d) R. Neidlein, and Z. Behzadi,
Chem.-Ztg
.,
100
, 388 - 389
(1976); e) R. Neidlein, and Z. Behzadi,
Chem.-Ztg
.,
102
, 150 - 152 (1978); f) R. C. Haddon, S. V. Chichester,
and J. H. Marshall,
Tetrahedron
,
42
, 6293 -6300 (1986).
58.
X. Chi, M. E. Itkis, B. O. Patrick,
et al
.,
J. Am. Chem. Soc
.,
121
, 10395 -10402 (1999).
59.
a) M. E. Itkis, X. Chi, A. W. Cordes, and R. C. Haddon,
Science
,
296
, 1443 -1445 (2002); b) X. Chi, M. E. Itkis,
K. Kirschbaum,
et al
.,
J. Am. Chem. Soc
.,
123
, 4041 - 4048 (2001); c) J. S. Miller,
Angew. Chem. Int. Ed
.,
42
,
27 - 29 (2003).
60.
X. Chi, M. E. Itkis, R. W. Reed,
et al
.,
J. Phys. Chem. B
,
106
, 8278 -8287 (2002).
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