Chemistry Reference
In-Depth Information
Figure 6.33 Diels-Alder reaction of anodically
generated quinone derivatives with diene on the
electrode surface modified with PTFE fibres
6.12.2 Electrolytic Reactions Using
Diamond Electrodes
Diamond is a solid crystal consisting of sp 3
carbons forming covalent bonds. It has
excellent transparency and thermoconductivity
as well as mechanical and chemical stability.
Although pure diamond is non-conductive, it
becomes electrically conductive by doping with
an impurity such as boron. Boron-doped
diamond films can be used as electrodes, which
exhibit excellent and superior electrochemical
properties compared to known metal and
carbon electrode materials. Accordingly,
boron-doped diamond (BDD) electrodes are
promising novel electrode materials [100].
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