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In addition, paired electrosynthesis was also
developed by the combination of anodic
oxidation and cathodic reduction using a
hydroxyl radical derived from H
2
O
2
and
various metal ion redox mediatory catalysts,
such as Fe
2+
/Fe
3+
, V
4+
/V
3+
, Cu
+
/Cu
2+
and
Ni
2+
/Ni
3+
.
Parallel paired electrochemical
polymer reaction:
Quite recently, Inagi,
Fuchigami and co-workers achieved the first
paired electrochemical polymer reactions of
conducting polymers, such as alternating
copolymers of 9-fluorenol and
9,9-dioctylfluorene adsorbed on an anode
and cathode to form a 9-fluorenone moiety
at the anode and a fluorene moiety at the
cathode, respectively [59]. Since the
reactions are solid phase, product isolation
is very easy.
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