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5.1.2. Dielectrophoresis in Media
For a particle with complex dielectric permittivity e p in a medium e m , the internal
electric displacement is the sum of the particle polarization and the external
displacement:
* i ¼ e p * i ¼ *
þ e m * i :
Therefore, the polarization scales with the internal electric field as
* i :
*
e p e m
¼
This polarization generates an additional surface charge dQ on each surface
element dF:
dF ¼ *
d *
dQ ¼ s pol
:
So, applying Coulomb's Law and combining this result with the unperturbed field,
we find that
ZZ
ZZ
h
i
* 12
4 pe m r 12
* 12
4 pe m r 12
* i ð * 1 Þ¼ * e ð * 1 Þ
dQ 2 ¼ * e ð * 1 Þ
*
ð * 2 Þ d * 2
ZZ
h
i
* 12
4 pe m r 12
¼ * e ð * 1 Þ e p e m
* i ð * 2 Þ d * 2
:
Since we assumed that the particle is linearly polarizable and, for approximation
purposes, considering only the polarization parallel to the electric field, it follows
that:
* i
*
¼ a * e ¼
e p e m
(
)
ZZ
h
i
* 12
4 pe m r 12
a
e p e m
* e ð * 1 Þ * e ð * 1 Þa Proj * e ð * 1 Þ
* e ð * 2 Þ d * 2
!
"
#
ZZ
* 12 * e ð * 1 Þ
* 2
* e ð * 2 Þ d * 2
r 12
a
e p e m
a
* e ð * 1 Þ * e ð * 1 Þ
4 pe m * e ð * 1 Þ
!
e ð * 1 Þ
e p e m
! a e m
"
#
ZZ
* 12 * e ð * 1 Þ
* 2
* e ð * 2 Þ d * 2
r 12
e p e m
4 p
e m þ
e ð * 1 Þ
e m is termed the Clausius-Mossotti factor and is
denoted by the frequency-dependent function K( o ).
The above expression for a
=
 
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