Environmental Engineering Reference
In-Depth Information
Table 3
Applied speciation steps for organotin determination in marine biota reported in papers published since 2000
Extraction
Derivatization
Preconcentration
Analysis
•
acid & polar solvent
•
organoborate
•
SPME [59]
•
GC-MS
-HCl,aceticacid
/
MeOH
- ethylation
[6, 20, 22, 30, 32, 33, 52, 55, 60]
•
[16, 17, 32, 33, 37, 51-53]
[17, 18, 33, 37, 38],
GC-FPD
•
acid & varying polarity solvent
[51, 52, 60, 68]
[17, 38, 53, 54, 57-59]
-HCl
/
toluene, diethyl ether, ethyl acetate
•
Grignard
•
GC-PFPD [16, 37, 68]
[22, 30, 54-56]
- pentylation
•
GC-ICP-MS [51]
•
basic digestion
[6, 20, 22, 30, 32],
•
GC-MS
/
MS [22]
- TMAH [18, 38, 57-60, 68]
[54, 55]
•
HPLC-ICP-MS [51]
•
PLE (ASE) [17, 51, 52]
- propylation [53]
•
HPLC-FD [56]
- sodium acetate & acetic acid
/
MeOH
