Environmental Engineering Reference
In-Depth Information
generally observed in the environment since the ban, particularly in areas
dominated by the small craft affected by the ban. However, in a few areas fre-
quented by large ships, the organotin compounds continue to be input to the
surface of the sediment, especially, in some harbors in Mediterranean coun-
tries such as Spain, Italy and Greece, and in northern Europe, etc.
Therefore, recently, the number of articles investigating depuration of the
organotin compounds by organisms have increased. Yamaoka et al. found two
kinds of microorganisms, Pseudomonas chlororaphis and Burkholderia cepa-
cia capable of degrading TPT. Dinoflagellates, diatoms, mussels, green algae
and chrysophytes, etc. are able to depurate TBT in seawater. Biomethylation
is also considered a depuration mechanism of the organotin compounds. The
results of these researches may be utilized for depuration of high concen-
tration areas of TBT and TPT such as areas frequented by the larger ships,
seawater near a dry dock and aquaculture with fish nets using organotin an-
tifouling paints. These may also be used for the treatment of waste water from
dry docks and for the treatment of cooling water from power plants.
Generally, recently, the concentration of organotin compounds in seawa-
ter has tended to decrease in the world through restrictions for small boats
and because of their fast degradation properties in seawater, though they have
accumulating properties in sediment and organisms. Furthermore, with the
help of these depuration technologies, we hope that the marine environment
improves in the world up to the point in time when environmentally friendly
best alternative antifouling paints are used routinely throughout the world.
Acknowledgements I would like to express my sincere appreciation to Dr. Sumio Chubachi
for reading the full manuscript, which enhanced its accuracy and clarity, and for provid-
ing much valuable constructive criticism.
References
1. Champ MA (2000) Sci Total Environ 258:21
2. Bosselmann K (1996) Environmental law and tributyltin in the environment In: de
More ST (ed) Tributyltin: Case Study of an Environmenal Contaminant. Cambridge
Environmental Chemistry Series 8. Cambridge University Press, Cambridge, p 237
3. Stewart C (1996) The efficacy of legistration in controlling tributyltin in the ma-
rine environment In: de More ST (ed) Tributyltin: Case Study of an Environmenal
Contaminant. Cambridge Environmental Chemistry Series 8. Cambridge University
Press, Cambridge, p 264
4. Ingham RK, Rosenberg SD, Gilman H (1960) Chem Rev 60:459
5. Hauge RF, Hastie JW, Margrave JL (1973) J Mol Spectrosc 45:420
6. Harrison PG (1998) Compounds of tin: general trends. In: Smith PJ (ed) Chemistry
of Tin, chap 2. Blackie Academic & Professional, London, p 18
7. Gillespie RJ, Nyholm RS (1957) Quart Revs (London) 11:339
8. Woodworth RC, Skell PS (1959) J Am Chem Soc 81:3383
9. Heeg MJ, Herber RH, Janiak C (1988) J Organomet Chem 346:321
10. Jensen KA, Clauson-Kass N (1943) Z Anorg U Allgem Chem 250:277
Search WWH ::




Custom Search