Environmental Engineering Reference
In-Depth Information
Table 2
Summary of developed LC-MS methods for the determination of antifouling booster biocides in marine water and sediment samples.
LC conditions and MS operation modes. Extraction methods and sensitivity (limits of detection, LOD)
Antifouling
Matrix
Extraction method
Recove- LC separation
Ionization Detection
Limit of detection
Refs.
(LOD, ng L
-1
booster
ries
mode
system
in
seawater and ng g
-1
biocides
(%)
Column
Mobile
phase
in sediment)
Irgarol 1051
seawater
SPE (C18)
88
VYDAC C18
Aq
/
ACN
DAD
3
[42]
/
sediment
centrifugation
103
VYDAC C18
Aq
ACN
DAD
2.1
[42]
(hexane:acetone)
seawater
SPE Prospekt (C18)
90-95
Shandon C8
Aq
/
ACN
DAD
1
[44, 48]
sediment
sonication (MeOH:
90
Shandon C8
Aq
/
ACN
APCI (+)
Shandon C8
no reported
[48]
water)
[30]
∗
seawater
SPE (C18)
96
Zorbax C18
Aq
/
ACN
DAD
11
[19, 48]
∗
seawater
SPE (polymeric)
106
Shandon C8
Aq
/
ACN
APCI (+)
5
[47]
∗
seawater
SPE (graphitized
81
LiChrosorb RP18
Aq
/
MeOH
APCI (+)
MS-Q (SIM)
4
carbon black)
seawater
SPE (polimeric)
88
Waters Sphrisorb Aq.AcNH
4
/
ESI (+)
MS-TQ
0.2
[32]
ODS2
MeOH
(MRM)
[50]
∗
sediment
sonication (MeOH:
99
Bakerbon ENV
Aq
/
ACN
APCI (+)
MS-IT (SIM)
0.001
EtAc)
seawater
SPE (polymeric)
95
Kromasil 100 C18 Aq.AcH
/
APCI (+)
MS-Q (SIM)
5
[51]
ACN
sediment
sonication
69
/
74
LiChrosorb RP18
Aq
/
MeOH
APCI (+)
MS-Q (SIM)
0.2
[52]
/
(MeHO
Acetone)
∗
simultaneous determination: ([19, 30, 31, 44, 47, 49, 50, 53])
