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a
a) (NH3) 2 Pt(3'-GMP) 2
b) pnPt(3'-GMP) 2
c) enPt(3'-GMP) 2
pH = 7
b
5
c
0
-5
250
300
nm
a) (NH3) 2 Pt(5'-GMP) 2
b) pnPt(5'-GMP) 2
c) enPt(5'-GMP) 2
pH = 7
8
a
b
4
c
0
-4
-8
250
300
nm
a) enPt(1-Me-5' GMP) 2
a
b) pnPt(1-Me-5' GMP) 2
6
pH = 7.8
4
b
2
0
-2
-4
-6
250
300
nm
Figure 5.10 CD spectra of cis -A 2 PtG 2 compounds when A 2 = (NH 3 ) 2 , pn, or en and G = 3
-
GMP, 5
-GMP, or 1-Me-5
-GMP (Ref. 105 for related work)
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