Chemistry Reference
In-Depth Information
a
a) (NH3)
2
Pt(3'-GMP)
2
b) pnPt(3'-GMP)
2
c) enPt(3'-GMP)
2
pH = 7
b
5
c
0
-5
250
300
nm
a) (NH3)
2
Pt(5'-GMP)
2
b) pnPt(5'-GMP)
2
c) enPt(5'-GMP)
2
pH = 7
8
a
b
4
c
0
-4
-8
250
300
nm
a) enPt(1-Me-5' GMP)
2
a
b) pnPt(1-Me-5' GMP)
2
6
pH = 7.8
4
b
2
0
-2
-4
-6
250
300
nm
Figure 5.10
CD spectra of
cis
-A
2
PtG
2
compounds when A
2
= (NH
3
)
2
, pn, or en and G = 3
′
-
GMP, 5
′
-GMP, or 1-Me-5
′
-GMP (Ref. 105 for related work)