Environmental Engineering Reference
In-Depth Information
Ta b l e 1
Phases and
components
Component
Phase
Wa t er
Oil
Gas
Solid
Oxygen,
O
2
X
Inert gas,
IG
X
Rock
X
Coke
X
Oil
X
Wa t er,
H
2
O
X
X
Kk
r
ʱ
μ
ʱ
u
ʱ
=−
(
∇
p
ʱ
−
ˁ
ʱ
g
) ,ʱ
=
o
,
w
,
g
,
(2)
μ
with
K
being permeability,
k
r
,
and
p
are relative permeability, viscosity and
pressure, respectively, whilst
g
is the gravity acceleration.
The energy balance assuming local thermal equilibrium is
ˁ
c
p
eq
∂
t
+∇·
ˆ
s
o
ˁ
o
c
p
,
o
u
o
+
s
w
ˁ
w
c
p
,
w
u
w
T
T
∂
s
g
ˁ
g
c
p
,
g
u
g
+
k
eff
·∇
T
(3)
q
o
q
g
q
w
+
q
s
=∇·
+
+
+
−
where
T
ˁ
o
c
p
,
o
−
ˁ
g
c
p
,
g
−
/
M
g
∂
s
o
∂
=
ˆ
c
g
R
t
(4)
ˁ
w
c
p
,
w
−
ˁ
g
c
p
,
g
−
/
M
g
∂
t
+
c
p
,
g
−
c
g
R
s
g
∂ˁ
g
∂
s
w
∂
c
g
R
t
ˁ
c
p
eq
=
ˆ
s
o
ˁ
o
c
p
,
o
+
s
g
ˁ
g
c
p
,
g
−
/
M
g
c
g
R
) ˁ
s
c
p
,
s
(5)
+
s
w
ˁ
w
c
p
,
w
+
(
1
/ˆ
−
1
with
k
eff
being the total thermal dispersion tensor,
q
T
the thermal source/sink,
T
the
temperature,
M
g
the average gas molecular weight,
c
p
the heat capacity,
c
g
the gas
compressibility, and
R
the ideal gas constant.
The oxygen balance is given by,
∂
ˆ
s
g
ˉ
gO
2
ˁ
g
∂
s
g
ˁ
g
D
gO
2
·∇
ˉ
gO
2
+∇·
ˆ
s
g
ˉ
gO
2
ˁ
g
u
g
=∇·
ˆ
+
R
O
2
(6)
t
And for coke we have that,
−
ˆ)
∂ (ˁ
s
ˉ
sCoke
)
∂
(
1
=
R
Coke
(7)
t
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