Chemistry Reference
In-Depth Information
Br
dpppNiCl
2
2.56
Cl Cl
dpppNiCl
2
MgCl
2.55
Br
2.58
Cl
Cl
dppeNiCl
2
2.57
Scheme 2.20
MgCl
Np
t
-Bu
2
P, Pd(OAc)
2
+
HN
HN
HN
Br
2.59
2.61
2.60
Scheme 2.21
Pd(OAc)
2
, PCy
3
, NMP
or
IMesPd.Naphthoquinone
BrMg
+
Cl
2.62
2.64
2.63
Scheme 2.22
NiCl
2
OTs
+ EtMgBr
Ph
Ph
2.66
2.65
Scheme 2.23
NiCl
2
Br
+
n
-PrMgBr
Br
2.67
Br
2.68
Scheme 2.24
Suzuki
HO
OSO
3
NH
thermal
nitrene
chemistry
MeO
2
C
N
OH
benzyne trapping-
Kumada coupling
HO
2.69
OH
HO
Scheme 2.25
