Chemistry Reference
In-Depth Information
OTBS
Ni(COD)
2
(
o
-biPhO)
3
P
OTBS
11.1
11.2
Scheme 11.1
OTBS
H
Ni(COD)
2
(
o
-biPhO)
3
P
OTBS
11.4
OTBS
H
•
11.3
[Rh(COD)Cl]
2
(
o
-biPhO)
3
P
11.5
Scheme 11.2
H
([(F
3
C)
2
CHO]
3
P)
3
RhCl
11.6
11.7
H
TBSO
TBSO
Scheme 11.3
SiMe
3
SiMe
3
[(C
8
H
14
)
2
RhCl]
2
, L*
O
O
H
11.8
11.9
87% e.e.
PPh
2
O
H
3
C
Ph
L* =
O
PPh
2
11.10
Scheme 11.4
H
(NBD)Rh(
S
)-BINAP SbF
6
O
O
H
11.11
11.12
> 98% e.e.
Scheme 11.5
