Chemistry Reference
In-Depth Information
N
N
N
Mo-catalys
t
H
2
, PtO
2
H
H
H
8
.
3
7
8.378
e.r. = 98:2
8
.
i
-Pr
i
-Pr
Ph
Mo
N
Mo-catalyst =
O
Cl
Cl
TBSO
8.380
Scheme 8.105
TBS
1. 9-BBN; H
2
O
2
, NaOH
2. TPAP, NMO
3. dppp
2
RhCl,
TBSO
O
Mo-catalyst
8.382
Δ
H
8.381
8.383
TBS
TBS
O
O
1. acacRh(CO)
2
,
CO, H
2
2. NaBH
4
1.
o
-O
2
NC
6
H
4
SeCl, Bu
3
P
2. mcpba
3. KNH(CH
2
)
3
NH
2
H
H
OH
8.384
8.385
TBS
O
HO
1. TBAF
2. CH
2
I
2
, Et
2
Zn
H
H
i
-Pr
8.386
8.387
THF
i
-Pr
Ar
Mo
Mo-catalyst =
Ph
O
O
8.382
Ar
Scheme 8.106
