Chemistry Reference
In-Depth Information
[Rh(cod)Cl]
2
, CO, H
2
,
i
-PrNH
2
+
N
i
-Pr
O
4.139
4.140
4.141
Scheme 4.53
[Rh(cod)Cl]
2
, CO, H
2
,
i
-PrNH
2
Ph
Ph
N
4.142
4.143
i
-Pr
Scheme 4.54
Rh(acac)(CO)
2
,
BIPHEPHOS
4.130
,
EtOH, CO, H
2
CO
2
Me
EtO
N
CO
2
Me
NH
t
-Boc
t
-Boc
4.144
4.145
n
-BuCu, BF
3
.OEt
2
n
-Bu
CO
2
Me
N
t
-Boc
4.146
Scheme 4.55
OH
Rh
2
(OAc)
4
,
P(OPh)
3
or biphephos
CO, H
2
Ts
OH
Ts
OsO
4
,
NMO
TsNH
N
N
n
-Pr
n
-Pr
n
-Pr
4.147
4.148
4.149
1. Ac
2
O, Et
3
N
2. CF
3
CO
2
H, Et
3
SiH
1. K
2
CO
3
, MeOH
2. Mg, MeOH, )))
OH
Ts
OAc
N
HN
n
-Pr
n
-Pr
4.150
4.151
Scheme 4.56
