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Scheme 5.36 Synthesis of rosin amine gluconolactone (N12)
The hydrophilicity of glycerol is weak but it can be improved by polymerisation
reactions. Rosin-based polyglycerol (N13) nonionic surfactants with different degrees
of polymerisation of polyglycerol were obtained ( Scheme 5.37 ) by an esterification
reaction [57]. Wang and co-workers reported that the nonionic surfactant polyglycerol
maleated rosin ester (N14) was synthesised by the reaction of maleated rosin and
polyglycerol ( Scheme 5.38 ). The relationships between the surface physicochemical
properties of the product and the degree of polymerisation of polyglycerol were
studied systematically [58].
Scheme 5.37 Synthesis of rosin-based polyglycerol (N13)
Scheme 5.38 Synthesis of maleic rosin polyglycerol (N14)
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