Geology Reference
In-Depth Information
Table 11.7: Thermodynamic properties of the upper continental crust
(Valero D. et al., 2012). - continued from previous page.
H
0
f i
,
kJ/mol
G
0
f i
,
kJ/mol
Mineral
Formula
i
, mol/g
Reference , %
b
chi
,
kJ/mol
Apatite
Ca
5
(PO
4
)
3
(OH)
0:33
F
0:33
Cl
0:33
7.91E-07
-6773.4
-6386.9
5
-7.2
Fe
2+
Al
9
Si
4
O
23
(OH)
Staurolite
7.68E-07
-12066.8
-11215.6
Faure (1991)
269.1
Talc
Mg
3
Si
4
O
10
(OH)
2
7.67E-07
-5907.2
-5543.0
Faure (1991)
22.6
Aragonite
CaCO
3
7.64E-07
-1207.9
-1128.6
Faure (1991)
11.4
Clinozoisite
Ca
2
Al
3
(SiO
4
)
3
(OH)
7.51E-07
-6883.9
-6483.9
Faure (1991)
53.0
Vermiculite
Mg
3
Si
4
O
10
(OH)
2
2(H
2
O)
6.78E-07
-7018.8
-5957.2
Faure (1991)
10
997.1
Mn
2+
2
Tephroite
(SiO
4
)
6.30E-07
-1733.3
-1632.1
Faure (1991)
199.3
Thomsonite
NaCa
2
Al
5
Si
5
O
20
6H
2
O
6.19E-07
-12413.7
-11543.9
1
-49.1
Zoisite
Ca
2
Al
3
Si
3
O
12
(OH)
5.68E-07
-6883.9
-5416.5
Faure (1991)
1120.4
Pyrolusite
MnO
2
5.64E-07
-520.4
-465.2
Faure (1991)
23.4
Anatase
TiO
2
5.59E-07
-940.4
-883.7
Faure (1991)
24.7
Ba
2
Mn
2+
2
Mn
4+
Psilomelane
1:2
O
10
2H
2
O
5.10E-07
-2569.1
-2347.2
1
465.2
Nepheline
Na
0:75
K
0:25
Al(SiO
4
)
5.09E-07
-2087.6
-1972.4
1
28.1
Forsterite
Mg
2
SiO
4
4.95E-07
-2175.5
-2057.8
Faure (1991)
63.6
NaAl
0:9
Fe
3+
Jadeite
0:1
(Si
2
O
6
)
4.78E-07
-2990.4
-2812.1
1
-2.7
Mn
2+
3
Spessartine
Al
2
(SiO
4
)
3
4.77E-07
-5646.3
-5326.3
Holland and
Powell (1998)
302.6
Monazite (Ce)
Ce
0:5
La
0:25
Nd
0:2
Th
0:05
(PO
4
)
4.29E-07
-2074.0
-1943.3
10
-43.3
Tremolite
Ca
2
Mg
5
Si
8
O
22
(OH)
2
4.28E-07
-12367.8
-11639.3
Faure (1991)
73.7
Na
2
Mg
2
Fe
2+
Al
2
(Si
8
O
22
)(OH)
2
Crossite
4.06E-07
-11600.3
-10925.8
1
89.3
Mn
2+
Mn
3+
6
Braunite
SiO
12
4.06E-07
-4260.0
-3944.7
Robie and Hem-
ingway (1995)
325.8
Chalcopyrite
CuFeS
2
3.62E-07
-194.6
-195.1
Robie and Hem-
ingway (1995)
1530.3
Sassolite
H
3
BO
3
3.60E-07
-1095.1
-969.0
Faure (1991)
19.7
Magnesite
MgCO
3
3.58E-07
-1114.1
-1030.2
Faure (1991)
15.6
Ti
0:7
Nb
0:15
Fe
2+
Ilmenorutile
0:225
O
2
3.22E-07
-864.6
-813.2
1
45.5
Witherite
BaCO
3
3.04E-07
-1217.1
-1137.6
Faure (1991)
44.1
Stilpnomelane
K
5
Fe
48
Al
5
Si
67
O
168
(OH)
48
36H
2
O
2.77E-07
-99933.0
-91181.96
0
4607.3
CaFe
2+
Si
2
O
6
Hedenbergite
2.75E-07
-2842.4
-2676.1
Faure (1991)
8651.4
Ba
0:8
Pb
0:2
Na
0:125
Fe
1:3
Al
0:2
Si
0:1
Mn
2+
0:5
Mn
4+
6
Hollandite
O
16
2.63E-07
-4733.3
-4330.4
1
288.3
Fe
2+
2
Fayalite
SiO
4
2.34E-07
-1480.9
-1369.2
Faure (1991)
246.6
Mn
2+
SiO
3
Rhodonite
2.32E-07
-1321.6
-1243.1
Faure (1991)
101.7
Cristobalite
SiO
2
2.06E-07
-910.1
-855.5
Faure (1991)
2.7
Pumpellyte
Ca
2
MgAl
2
(SiO
4
)(Si
2
O
7
)(OH)
2
H
2
O
1.89E-07
-7148.6
-6672.5
1
57.9
Phlogopite
KMg
3
AlSi
3
O
10
F(OH)
1.58E-07
-6292.8
-5902.2
1
128.1
Manganite
MnO(OH)
1.55E-07
-622.4
-557.3
10
49.4
Fluorite
CaF
2
1.44E-07
-1220.5
-1168.1
Faure (1991)
111.9
Amblygonite
Li
0:75
Na
0:25
Al(PO
4
)F
0:75
(OH)
0:25
1.29E-07
-307.1
-282.7
10
1998.6
Vesuvianite
Ca
10
Mg
2
Al
4
(SiO
4
)
5
(Si
2
O
7
)
2
(OH)
4
1.20E-07
-21175.8
-19948.7
Holland and
Powell (1998)
219.0
Mn
2+
0:6
Fe
2+
0:3
Mg
2+
Fe
3+
1:5
Mn
3+
Jacobsite
0:5
O
4
1.20E-07
-1237.4
-1137.5
5
711.5
Bastnaesite
La(CO
3
)F
1.16E-07
-1660.9
-1527.8
5
160.8
Na
3
Fe
2+
4
Fe
3+
(Si
8
O
22
)(OH)
2
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