Environmental Engineering Reference
In-Depth Information
Table 10.5 ( Cont .)
Adsorbent
Dye
q max
Reference
Pumpkin seed hull
Basic Blue 9
141.92
[138]
Raw date pits
Basic Blue 9
80.3
[31]
Rice hull ash
Direct Red 28
171
[139]
Rice husk
Basic Red 2
838
[27]
Rice husk
Basic Blue 9
312
[27]
Sugar beet pulp
Gemazol Turquoise Blue-G
234.8
[140]
Sugar cane dust
Basic Green 4
4.88
[141]
Sugar-industry-mud
Basic Red 22
519
[142]
Tree fern
Basic Red 13
408
[12]
Treated Parthenium
Basic Blue 9
88.49
[143]
Treated sawdust
Basic Green 4
74.5
[118]
Treated sawdust
Basic Green 4
26.9
[118]
Vine
Basic Red 22
210
[144]
Vine
Basic Yellow 21
160
[144]
Wood sawdust
Basic Blue 69
74.4
[145]
Wood sawdust
Acid Blue 25
5.99
[145]
of its low cost and high availability, bark is very attractive as an adsor-
bent. Palma et al. [120] reported that, like sawdust, the cost of forest wastes
is only associated with the transport cost from the storing place to a site
where they will be utilized. Bark is an effective adsorbent because of its
high tannin content [121,122]. The polyhydroxy polyphenol groups of tan-
nin are thought to be the active species in the adsorption process. There
are promising perspectives for the utilization of bark as adsorbent on an
industrial scale. However, the adsorption mechanisms are not clearly iden-
tified. Tree fern, an agricultural byproduct, was also proposed to remove
pollutants from aqueous solutions [123,12]. This is a complex material
containing lignin and cellulose as major constituents, giving interesting
adsorption capacity values. The adsorption mechanism is due to chemi-
sorption (mainly ion-exchange).
10.7 Industrial Byproducts
Industrial solid wastes such as metal hydroxide sludge, fly ash and red mud
can be used as low-cost and locally available adsorbents for dye removal,
 
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