Environmental Engineering Reference
In-Depth Information
Table 5.17
Comparison of adsorption capacities of palm waste-based materials.
Modification
Surface
Area
(
m
2
g
-1
)
Dye Type
pH
Adsorption
Capacity
(
mg
.
g
-1
)
Ref.
N/A
…
Methylene Blue
6.3
39.5
[81]
N/A
…
Methylene Blue
7.1
655.9
[96]
N/A
…
Azo Dye
5
38.6
[97]
N/A
…
Methyl Violet
10
96.3
[98]
N/A
…
Basic Yellow 21
…
327.6
[125]
Besic Red 22
180.3
Basic Blue 3
91.3
Basic Red 18
242
[126]
N/A
…
Methylene Blue
7
95.4
[127]
Crystal Violet
78.9
Carbonization - KOH -
CO
2
Activation
1354
Methylene Blue
6.5
275.7
[99]
Carbonization - KOH -
CO
2
Activation
596.2
Methylene Blue
6.5
241
[128]
Carbonization - KOH -
CO
2
Activation - HCl
…
Methylene Blue
6.5
303
[129]
Carbonization - KOH -
Microwave irradiation
707.8
Methylene Blue
…
312.5
[101]
Carbonization - KOH -
Microwave irradiation
1223
Methylene Blue
12
382.3
[102]
Carbonization - KOH -
Microwave irradiation
807.5
Methylene Blue
12
344.8
[130]
of this waste showed that it contains a number of functional groups, such
as
N - H, C - O - H, C = O, C-N
and
P -H
. The comparison of the detected
peaks before and after the dye adsorption process revealed the presence of
amine, carbonyl and carboxyl groups in the adsorption process. The meth-
ylene blue uptake capacity of 70.9
mg.g
-1
was observed at a pH value of
7 and an adsorbent dosage of 1 .
L
-1
, which was further enhanced when the
pH level was increased up to 10. Cazetta
et al.
[109] successfully attempted
to produce high surface area activated carbon from coconut shell by a mix-
ture of chemical and physical activation methods. The waste precursor
was charred at 500 C under nitrogen atmosphere. Then the prepared char
was impregnated at NaOH at various ratios and subsequently activated at
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