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Ziegler T., Macromol. Symp . 2001 , 173 ,
163-177; h) Zurek E., Ziegler T., Orga-
nometallics 2002 , 21(1) , 83-92; i) Chan
M. S.W., Vanka K., Pye C.C., Ziegler T.,
Organometallics 1999 , 18(22) , 4624-4636;
j) Deng L.Q., Ziegler T., Woo T. K.,
Margl P., Fan L. Y., Organometallics
1998 , 17(15) , 3240-3253.
7 Beck S., Brintzinger H.-H., Suhm J.,
Mülhaupt R., Macromol. Rapid Com-
mun. 1998 , 19(5) , 235-239.
8 For older reports on late transition metal
olefin catalysis, see for example a) Osto-
ja Starzewski K. A., Witte J. in: Transi-
tion Metals Catal. Polym., [Proc. Int.
Symp.], Quirk R. P. (ed.), Cambridge
University Press, Cambridge, UK 1988 ,
pp. 472-96; b) Ostoja Starzewski K. A.,
Witte J., Angew. Chem . 1985 , 97(7) , 610-
12, and in (c) Ittel S.D., Johnson L. K.,
Brookhart III M., Chem. Rev. 2000 , 100 ,
1169; d) Klabunde U., Ittel S.D., J.
Mol. Catal. 1987 , 41 , 123.
9 A simple analysis may be performed by
counting the patents in which the poly-
merization of 1-olefins with late transi-
tion metal catalysts is claimed. The fol-
lowing results ( year : # of patents) are
reached: 1994 : 67, 1995 : 59, 1996 : 64,
1997 : 75, 1998 : 102, 1999 : 100, 2000 : 143,
2001 : 132. These include for example a)
Bennett A.M.A. (DuPont), WO 98/
27124, 1998 ;b)Britovsek G. J. P., Dorer
B. A., Gibson V.C., Kimberley B. S., So-
lan G. A. (BP Chemicals Ltd.), WO 99/
12981, 1999 ;c)Bennett A.M.A. (Du-
Pont), WO 99/51550, 1999 ;d)Brook-
hart M. S., Small B. L. (DuPont), WO
98/30612, 1998 . Moody L. S., Mackenzie
P. B., Killian C.M., La Voie G.G., Po-
nasik J. A., Barrett A.G.M., Smith
T.W., Pearson J. C. (Eastman Chemical
Company), WO 00/50470, 2000 . Gibson
V. C., McTavish S. J.
Sesto B., Consiglio G., J. Am. Chem.
Soc . 2001 , 123(17) , 4097-4098.
11 Reviews: a) Britovsek G. J. P., Gibson
V. C., Wass D. F., Angew. Chem. 1999 ,
111 , 448; Angew. Chem. , Int. Ed. Engl.
1999 , 38 , 428; b) Ostoja; Mecking S., Co-
ord. Chem. Rev. 2000 , 203 , 325; c) Meck-
ing S., Angew. Chem. 2001 , 113 , 550; An-
gew. Chem. , Int. Ed. Engl. 2001 , 40 , 534.
a) Killian C.M., Tempel D. J., Johnson
L. K., Brookhart M., J. Am. Chem. Soc.
1996 , 118 , 11665; b) Johnson L. K.,
Mecking S., Brookhart M., J. Am.
Chem. Soc. 1996 , 118 , 267; c) Feldman
J., McLain S. J., Parthasarathy A.,
Marshall W. J., Calabrese J.C., Arthur
S.D., Organometallics 1997 , 16 , 1514; d)
Killian C.M., Johnson L. K., Brook-
hart M., Organometallics 1997 , 16 , 2005;
e) Mecking S., Johnson L. K., Wang L.,
Brookhart M. J. Am. Chem. Soc. 1998 ,
120 , 888; f) Tempel D. J., Brookhart M.,
Organometallics 1998 , 17 , 2290; g) Svejda
S.A., Brookhart M., Organometallics
1999 , 18 , 65; h) Svejda A. S., Johnson
L. K., Brookhart M., J. Am. Chem. Soc.
1999 , 121 , 10634; i) Peruch F., Cramail
H., Deffieux A., Macromolecules 1999 ,
32 , 7977; j) Tempel D. J., Johnson L. K.,
Huff R. L., White P. S., Brookhart M.,
J. Am. Chem. Soc. 2000 , 122 , 6686; k)
Gates D. P., Svejda S.A., Onate E., Kill-
ian C.M., Johnson L. K., White P. S.,
Brookhart M., Macromolecules 2000 , 33 ,
2320; l) Pappalardo D., Mazzeo M.,
Antinucci S., Pellechia, C., Macromole-
cules 2000 , 33 , 9483; m) Schmid M.,
Eberhardt R., Klinga M., Leskelä M.,
Rieger B., Organometallics 2001 , 20 ,
2321; n) Ostoja; Hicks F. A., Brookhart
M., Organometallics 2001 , 20(15), 3217-
3219.
12
a) Britovsek G. J. P., Gibson V.C., Kim-
berley B. S., Maddox P. J., McTavish
S. J., Solan G. A., White A. J. P., Wil-
liams D. J., Chem. Commun . 1998 , 849;
b) Britovsek G. J. P., Bruce M., Gibson
V. C., Kimberley B. S., Maddox P. J.,
Mastroianni S., McTavish S. J., Red-
shaw C., Solan G.A., Strömberg S.,
White A. J. P., Williams D. J., J. Am.
Chem. Soc . 1999 , 121 , 8728; c) Britovsek
G. J. P., Mastroianni S., Solan G. A.,
13
(BP Chemicals Ltd.),
WO 00/08034, 2000 .
10 For a recent review, compare for Bian-
chini C., Meli A., Coord. Chem. Rev.
2002 , 225(1-2) , 35-66. Newer develop-
ments a) Klaui W., Turkowski B.,
Chenskaya T. B., Z. Anorg. Allg. Chem.
2001 , 627(12) , 2609-2614; b) Nozaki K.,
Shibahara F., Elzner S., Hiyama T.,
Can. J. Chem. 2001 , 79(5) , 593-597; c)
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