Environmental Engineering Reference
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Figure 1. Example of triangular simplex region from three-component mixture
experiment.
‗e' is the random error term, represents the combined effects of all
variables not included in the model. For a mixture experiment, x 1 + x 2
+ x 3 = 1 therefore, the model can be re-written as:
y = b 1 x 1 + b 2 x 2 + b 3 x 3 + e
(2)
where,
b* 0 = b* 0 . (x 1 + x 2 + x 3 )
This form is known as the Scheffé linear mixture polynomial [2]
Similarly, the quadratic polynomial is as follows:
y = b 0 + b * 1 x 1 + b * 2 x 2 + b * 3 x 3 + b * 12 x 1 x 2 + b * 13 x 1 x 3 + b * 23 x 2 x 3 + b * 11 x 1 2 +
b * 22 x 2 2+ b 33 x 3 2 + e
(3)
Again this can be represented as:
y = b 1 x 1 + b 2 x 2 + b 3 x 3 + b 12 x 1 x 2 + b 13 x 1 x 3 + b 23 x 2 x 3 + e
where,
x 1 2 = x 1 .(1- x 2 - x 3 )
x 2 2 = x 2 .(1- x 1 - x 3 )
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