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d Vapor pressure and aqueous solubility at 298 K except where noted. For solids and gases the values are
for the subcooled liquid state (Ambrose and Ghiasse, 1987; Cal, 2006; Helburn et al., 2008).
e Verschuren (1983), Schwarzenbach et al. (1993), and Montgomery (1996).
f Values for pentachlorophenol are for the solid species.
g For nitrophenols the values are for subcooled liquid species at 293 K (Schwarzenbach et al., 1988).
Values of log K ow are for the neutral species.
h Values for solids and gases are for subcooled liquid state at 298 K (Mackay et al., 1992; Schwarzenbach
et al., 1993; Sarraute et al., 2008).
i Values from Iverfeldt and Lindqvist (1984), Mason et al. (1996), and Stein et al. (1996).
j Values from Mazzoni et al. (1997).
k Organization for Economic Co-operation and Development: Joint meeting of the chemical commit-
tee and the working party on chemicals, pesticides, and biotechnology: Hazard assessment of PFOS,
ENV/JM/RD(2002)17/Final (2002).
l Li et al. (2007).
m PBDEs are commercial mixtures and consist of PeBDE (penta-, tetra-, and hexa-BDE), OBDE (hepta-,
octa-, and hexa-BDE), DBDE (deca- and nona-BDE). Data from Environment Canada: Ecological
Screening Assessment Report on PBDEs, June 2006.
n Hansch et al. (1995), Lee et al. (1996), Ruelle (2000),Yaffe et al. (2001), and Ji et al. (2008).
Note: Excellent compilations of physicochemical properties for a variety of chemicals can be found
at the following sites on the worldwide web: (a) http://webbook.nist.gov chemistry and (b)
http://www.chemfinder.camsoft.com.
REFERENCES
Amrose, D. and Ghiassee, N.B. 1987. Vapor pressures and critical temperatures and critical
pressures of some alnoic acids: C 1 to C 10 . Journal of Chemical Thermodynamics 19,
505-517.
Cal, K. 2006. Aqueous solubility of liquid monoterpenes at 293K and relationship with
calculated log P value. Yakugaku Zasshi 126, 307-310.
Hansch, C., Leo, A., and Hoekman, D. 1995. Exploring QSAR-Hydrophobic, Electronic and
Steric Constants . Washington, DC: American Chemical Society.
Helburn, R., Albritton, J., Howe, G., Michael, L., and Franke, D. 2008. Henry's law constants
for fragrance and organic solvent compounds in aqueous industrial surfactants. J Chem.
Eng. Data 53, 1071-1079.
Iverfeldt,A. and Lindqvist, O. 1984.The transfer of mercury at the air-water interface, Proceed-
ingsoftheInternationalSymposiumonGastransferatWaterSurfaces, ReidelPublishing
Co., NewYork, pp. 533-538.
Ji, C. and Evans, M.E. 2007. Using an internal standard method to determine Henry's law
constants. Environmental Toxicology and Chemistry 26, 231-236.
Ji, C., Boisvert, S.M., Arida, A.C., and Day, S.E. 2008. Measurement of Henry's law constant
using internal standard: A quantitative GC experiment for the instrumental analysis or
environmental chemistry laboratory. Journal of Chemical Education 65, 369-372.
Leo, A., Hansch, C., and Elkins, D. 1971. Paritition coefficients and their uses. Chem. Rev. 71,
525-613.
Li, H., Ellis, D., and Mackay, D. 2007. Measurement of low air-water partition coefficients of
organic acids by evaporation from a water surface, JournalofChemicalandEngineering
Data 52, 1580-1584.
Mackay, D., Shiu, W.Y., and Ma, K.C. 1992. Illustrated Handbook of Physical-Chemical
Properties and Environmental Fate for Organic Chemicals . Chelsea, MI: Lewis
Publishers.
 
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