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Similarly, at position ( x , y C dy , z )wehave:
Now we shall prove that this is a consequence of
the Larmor precession discussed in Sect. 3.2 .We
have shown in Sect. 3.2 that the electron orbits are
magnetic dipoles, with a definite magnetic mo-
ment that depends from the angular momentum
(Eq. 3.17 ). In normal conditions, the atoms of a
diamagnetic substance have a net magnetic mo-
ment equals zero, because the various magnetic
moments, associated with orbits, electron spins,
etc., balance out. However, when we apply an
external magnetic field, the precession of an elec-
tron orbit about the field direction is equivalent
to an additional microscopic current loop having
radius a and an intensity that according to ( 3.16 )
is given by:
I.x;y C dy; z / D M z .x;y C dy; z /d z
M z .x;y; z / C
@y dy d z
(3.42)
@M z
D
Therefore, it is evident from Fig. 3.9 that a
first contribution to the net macroscopic current
flowing in direction x is:
@M z
@y dyd z
•I .x/
1 D
(3.43)
Another contribution to the current flowing
in the x direction can be obtained considering a
thin slice of thickness dy , parallel to plane xz at
elevation y . At position ( x , y , z ), the existence of a
non-zero component of magnetization M y ( x , y , z )
is equivalent to the existence of an infinitesimal
rectangular coil having area dxdz and magnetic
moment dm y D M y ( x , y , z ) dxdydz .Bythesame
reasoning as before, we see that an additional
contribution to the macroscopic current in the x
direction will be:
L
I L D
(3.46)
This current is associated with an extra angular
momentum, resulting from the twist of the elec-
tron orbit, which is parallel to the external field:
1
2 ea 2
•L D m e a v L B ext D m e a 2 ¨ L B ext D
B ext
(3.47)
@M y
@ z dyd z
wherewehaveused( 3.20 ). It should be noted
that • L represents an additional vector of angu-
lar momentum and not the variation of L in a
small time interval, which is indicated as d L (see
Fig. 3.5 ). According to ( 3.17 ), this extra angular
momentum must be associated with an additional
magnetic moment, • m , given by:
•I .x 2 D
(3.44)
Therefore, the total macroscopic current in the
x direction is given by:
@M y
@ z
dyd z
@M z
@y
D •I .x 1 C •I .x 2 D
•I .x/
j mx dyd z
(3.45)
e 2 a 2
4m e B ext
e
2m e •L D
•m D
(3.48)
This proves that the components of the curl
of M coincide with the components of a net
macroscopic current density, resulting from the
microscopic currents that flow within the body.
The magnetization acquired by a body in pres-
ence of an external magnetic field is called in-
duced magnetization and is in general a function
of the applied field B ext . The relation between M
and B ext is different among the three classes of
magnetic behavior of matter. We have mentioned
that all the ordinary substances acquire a weak
magnetization that opposes B ext (diamagnetism).
Thus, the extra magnetic moment • m opposes
the external field B ext . Regarding the quantity a 2
that appears in ( 3.48 ),itcanbeshownonthe
basis of quantum mechanics considerations that
it represents the averaged square distance of the
electron from the axis of B ext (e.g., Feynman et al.
2006 ). If the external field is aligned with the z -
axis and r ( x , y , z ) is the instantaneous position
of the electron, then a 2
Dh x 2
iCh y 2
i . For a spher-
ically symmetric atom, h x 2
i ,
where r is the distance of the electron from
iDh y 2
iDh z 2
iDh r 2
 
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