Environmental Engineering Reference
In-Depth Information
Problem 10.8
This plant substitutes NG (formula CH
4
) instead of coal, with a heating value of 50 MJ/kg, in a
combined cycle mode having a thermal efficiency of 45%. (a) How much NG (m
3
/y at STP) is
consumed? (b) How much CO
2
(t/y) is emitted?
Problem 10.9
In order to ameliorate the CO
2
caused greenhouse effect, a power plant is built that enables the
capture of CO
2
from the flue gas. The plant runs on pure methane and oxygen, so the flue gas
consists only of CO
2
and H
2
O:
CH
4
+
2O
2
→
CO
2
+
2H
2
O
−
0
.
244 kWh(th)/mole CH
4
where the minus sign means that the process is exothermic; that is, energy is evolved. The plant must
produce its own O
2
. From oxygen suppliers we know that the energy requirement for air separation
is 250 kWh (electric) per metric ton of O
2
. An equal amount of electric energy is required for
liquefaction of 1 metric ton of CO
2
. The plant has a gross thermal efficiency
45 (that
is, thermal efficiency calculated before electricity is syphoned off for O
2
production and CO
2
liquefaction). (a) What percentage of the plant's electricity output is available for dispatch into the
grid? (b) What is the net thermal efficiency (electricity output per heat input after O
2
production
and CO
2
liquefaction)?
η
gross
=
0
.
Brown, M. A., M. D. Levine, J. P. Romm, A. H. Rosenfeld, and J. G. Koomey, 1998. Engineering-Economic
Studies of Energy Technologies to Reduce Greenhouse Gas Emissions: Opportunities and Challenges.
Annu. Rev. Energy Environ.,
23,
287-387.
Eliasson, B., P. W. F. Riemer, and A. Wokaun, Eds., 1999.
Greenhouse Gas Control Technologies.
Amsterdam:
Pergamon Press.
Herzog, H., D. Golomb, and S. Zemba, 1991.
Feasibility, Modeling and Economics of Sequestering Power
Plant CO
2
Emissions in the Deep Ocean
. Environ. Prog.,
10,
64-74.
Houghton, J. T., 1997.
Global Warming
. Cambridge: Cambridge University Press.
Mahlman, J. D., 1998. Science and Nonscience Concerning Human-Caused Climate Warming.
Annu. Rev.
Energy Environ.,
23,
83-107.
Matthai, C. V., and G. Stensland, Eds., 1994.
Global Climate Change: Science, Policy and Mitigation Strate-
gies.
Pittsburgh: Air and Waste Management Association.
Mitchell, J. F. B., 1989. The Greenhouse Effect and Climate Change.
Rev. Geophys.,
27,
115-139.
Omerod, B., 1994.
The Disposal of CO
2
from Fossil Fired Power Stations.
Cheltenham: IEA Publications.
Ramanathan, V., and J. A. Coakley, 1978. Climate Modeling through Radiative-Convective Models.
Rev.
Geophys. Space Phys.,
16,
465-490.
Riemer, P., 1993.
The Capture of CO
2
from Fossil Fired Power Stations.
Cheltenham: IEA Publications.
Schneider, S. H., 1989. The Greenhouse Effect: Science and Policy.
Science,
243,
771-781.