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Fig. 4.3 Electron
microscopy of cuticles of
fossil weevils from Enspel
and a modern weevil
Sitophilus zeamais for
comparison. ( a , b ) SEM,
( c , d ) TEM. ( a , b , d ) Fossil
weevil, ( c ) modern weevil;
( a ) shows outer surface of
cuticle and ( b ) broken inner
surface of cuticle. ( c , d )
shows outer exocuticle
and inner multilayered
endocuticle; in ( c ) the
exocuticle is thicker
and it has also been slightly
distorted during sectioning
giving an undulating
appearance. Scale bars:
10 μ m in ( a ) and ( b ),
1 μ m in ( c ) and ( d )
Lignin preservation is in the form of guaiacyl units but no syringyl-related lignin
units were detected. Polysaccharide moieties detected include 2-methyl-2-
cyclopenten-2-one, 2,3-dimethyl cyclopenten-1-one and an unknown pyrolysis
product characterised by m/z 68,79,93 fragment ions that is very likely derived from
polysaccharide (Bland et al. 1998 ). Methyl indole, benzene and its alkyl derivatives
(C 2 to C 4 ), napthalene and pristenes were also present in the pyrolysate.
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