Chemistry Reference
In-Depth Information
The primary integral gives
ς
dz
2
+sin 2 θ = k 2 ,
(6.8)
where k 2 < 1 and k 2 is the integral constant. The further integral gives
the relation of θ and z as
= θ
0
1
k
z
ς
= F ( θ, k ) ,
(6.9)
k 2 sin 2 θ ) 2
(1
where F ( θ, k ) is the elliptic integral of the first kind. In the absence of
a magnetic field, no deformation occurs and the twist angle is a linear
function of z . But as a magnetic field is applied, the dependence of θ on z
is no longer a linear function. The Elliptic integral of the first kind F ( θ, k )
is a periodic function with the period 4 K ( k ) where K ( k )
F ( π/ 2 ,k ), the
complete elliptic integral of the first kind. Thus the helical pitch P for a
magnetic field H is
P =4 kςK ( k )
(6.10)
and the integral constant k is expressed implicitly by
E ( k )
k
= π 2 ςP 0 ,
(6.11)
where E ( k )= π/ 2
0 (1 k 2 sin 2 θ ) 2 , is the complete elliptic integral of the
second kind. Substituting it into Equation 6.10 then yields the ratio of the
current to intrinsic helical pitch as
P/P 0 = 2
π
2
K ( k ) E ( k )
(6.12)
If k is small, the ratio is rewritten approximately as
P 0
ς
4
P 0 1+ 1
P
.
(6.13)
32
It is noted that for a small magnetic field, the helical pitch increases
slowly until k 2 = 1 at which one has E ( k )=1and K ( k )
→∞
and then
P/P 0
→∞
.
(6.14)
 
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