Environmental Engineering Reference
In-Depth Information
(a)
(b)
S
Au
Au
Emission
Excitation
450
600
750
900
400
600
800
Wavelength (nm)
Wavelength (nm)
FIGURE 26.1
(a) UV/Vis optical absorption spectrum of Au
25
(SG)
18
cluster. (b) Photoluminescence spectra of Au
25
(SG)
18
, which
exhibits emission at 690 nm. (Adapted from Shibu, E.S. et al.,
J. Phys. Chem C
., 112, 12168, 2008. Copyright with
permission from American Chemical Society.) Inset: crystal structure of Au
25
(SCH
2
CH
2
Ph)
18
. Total structure
is assumed as a shell of six (-RS-Au-SR-Au-SR-) units sitting on an Au
13
core. (Adapted from Zhu, M. et al.,
J. Am. Chem. Soc
., 130, 5883, 2008. Only Au and S atoms are shown. Copyright with permission from American
Chemical Society.)
1995
2025
Water withdrawal as percentage of
total available
Over 40%
40%-20%
20%-10%
Less than 10%
FIGURE 27.1
Water withdrawal rate as a percentage of total available water, projected till 2025. (From Service, R.F.,
Science
,
313, 1088, 2006.)