Environmental Engineering Reference
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where
β
and
σ
are the volume fractions of the
β
-and
σ
-phases with
β = ϕ
,
σ =
for a rigid two-phase system.
Quintard andWhitaker (1993) substitute Eqs. (6.263) and (6.264) into Eqs. (6.259)
and (6.260) to obtain
1
ϕ
with a constant porosity
ϕ
) β T β β
= · (
β ) ,
β ( ρ
c
k
β
T
(6.265)
t
and
T σ σ
) σ
σ ( ρ
c
= · (
k σ
T σ ) .
(6.266)
t
Next Quintard and Whitaker (1993) apply the spatial averaging theorem (Theo-
rem 5.2 in Wang et al. 2007b) to Eqs. (6.265) and (6.266) and neglect variations
of physical properties within the REV. The result is
k β
β T β β + T β β β +
n βσ T β d A
) β T β β
1
V REV
β ( ρ
c
= ·
t
A
βσ
accumulation
conduction
1
V REV
+
n βσ ·
k β
T β d A
,
A
βσ
interfacial flux
(6.267)
and
k σ
n βσ T σ d A
) σ T σ σ
1
V REV
T σ σ +
T σ σ σ +
σ ( ρ
c
= ·
σ
t
A
βσ
accumulation
conduction
1
V REV
+
n βσ ·
k σ
T σ d A
.
A
βσ
interfacial flux
(6.268)
By introducing the spatial decompositions T β = T β β
T σ σ +
T σ and by applying scaling arguments and Theorem 5.2 in Wang et al. 2007b,
Eqs. (6.267) and (6.268) are simplified into (Quintard and Whitaker 1993)
T β
+
and T σ =
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