Environmental Engineering Reference
In-Depth Information
tems. First, they define the microscale problem by the first law of thermodynamics
and the Fourier law of heat conduction (Fig. 6.8)
)
β
∂
T
β
∂
(
ρ
c
t
=
∇
·
(
k
β
∇
T
β
)
,
in the
β
-phase
(6.253)
)
σ
∂
T
σ
∂
(
ρ
c
t
=
∇
·
(
k
σ
∇
T
σ
)
,
in the
σ
-phase
(6.254)
T
β
=
T
σ
,
at the
β
−
σ
interface
A
(6.255)
βσ
n
βσ
·
k
β
=
n
βσ
·
k
σ
∇
T
σ
,
at the
β
−
σ
interface
A
βσ
(6.256)
Here
,
c
and
k
are the density, specific heat and thermal conductivity, respectively.
Subscripts
ρ
β
and
σ
refer to the
β
-and
σ
-phases, respectively.
A
represents the
βσ
interface contained in the REV,
n
βσ
is the outward-directed surface
normal from the
area of the
β
−
σ
n
σβ
(Fig. 6.8). To be
thorough, Quintard and Whitaker (1993) have also specified the initial conditions
and the boundary conditions at the entrances and exits of the REV; however, we
need not do so for our discussion.
Next Quintard and Whitaker (1993) apply the superficial averaging process to
Eqs. (6.253) and (6.254) to obtain,
β
-phase toward the
σ
-phase, and
n
βσ
=
−
1
V
REV
)
β
∂
T
β
∂
1
V
REV
(
ρ
c
d
V
=
∇
(
k
β
∇
T
β
)
d
V
,
(6.257)
t
V
β
V
β
and
1
V
REV
)
σ
∂
T
σ
∂
1
V
REV
σ
(
ρ
c
d
V
=
σ
∇
·
(
k
σ
∇
T
σ
)
d
V
,
(6.258)
t
V
V
Fig. 6.8
Rigid two-phase system
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