Environmental Engineering Reference
In-Depth Information
tems. First, they define the microscale problem by the first law of thermodynamics
and the Fourier law of heat conduction (Fig. 6.8)
) β
T β
( ρ
c
t = · (
k β
T β ) ,
in the
β
-phase
(6.253)
) σ
T σ
( ρ
c
t = · (
k σ
T σ ) ,
in the
σ
-phase
(6.254)
T
β =
T σ ,
at the
β σ
interface A
(6.255)
βσ
n βσ ·
k β =
n βσ ·
k σ
T σ ,
at the
β σ
interface A βσ
(6.256)
Here
, c and k are the density, specific heat and thermal conductivity, respectively.
Subscripts
ρ
β
and
σ
refer to the
β
-and
σ
-phases, respectively. A
represents the
βσ
interface contained in the REV, n βσ is the outward-directed surface
normal from the
area of the
β σ
n σβ (Fig. 6.8). To be
thorough, Quintard and Whitaker (1993) have also specified the initial conditions
and the boundary conditions at the entrances and exits of the REV; however, we
need not do so for our discussion.
Next Quintard and Whitaker (1993) apply the superficial averaging process to
Eqs. (6.253) and (6.254) to obtain,
β
-phase toward the
σ
-phase, and n βσ =
1
V REV
) β
T β
1
V REV
( ρ
c
d V
=
(
k β
T β )
d V
,
(6.257)
t
V
β
V
β
and
1
V REV
) σ
T σ
1
V REV
σ ( ρ
c
d V
=
σ · (
k σ
T σ )
d V
,
(6.258)
t
V
V
Fig. 6.8 Rigid two-phase system
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