Environmental Engineering Reference
In-Depth Information
C 0 m 1
m 1 m 2
C 1 m 2 exp
m 2 ðÞþ
exp
m 1 ðÞ¼
0
(5.15)
which leads to the solution:
c in m 2 m 2 m 1
ð
Þ
exp
m 2 ðÞ
C 0 ¼
m 1 exp
m 1 ðÞ m 2 exp
m 2 ðÞ
(5.16)
c in m 1 exp
m 1 ðÞ
C 1 ¼
m 1 exp
m 1 ðÞ m 2 exp
m 2 ðÞ
.
This will be done in the next sub-chapter. Here, we want to point out that the given
procedure can be applied to obtain the solution for different types of boundary
conditions. In all cases the free constants C 0 and C 1 in a formula for the general
solution, like in ( 5.13 ), have to be determined to fulfil the conditions. For Dirichlet
boundary conditions on both sides
With these formulae the solution is complete to be computed in MATLAB
®
0
Þ¼c in and cðLÞ¼c 0 one obtains:
c in m 2 m 1
ð
Þ
exp
m 2 ðÞ
C 0
m 1 m 2
C 0 ¼
C 1 ¼ c in
(5.17)
exp
m 1 ðÞ
exp
m 2 ðÞ
Higher order decay usually is much more difficult to handle than decay of first
order. In order to tackle more complex formulations MATLAB ® offers the possi-
bility to use numerical methods for ordinary differential equations. Such methods
are treated in Chap. 9.
5.3 Dimensionless Formulation
In dimensionless form the solution ( 5.13 ) can be written as:
exp
c ð x Þ
c in ¼ C 0 exp
C 0
ðÞþ
m 1
1
ðÞ
m 2
(5.18)
with dimensionless depth x ¼ x=L; m 1 ¼ m 1 L; m 2 ¼ m 2 L and one integration con-
stant C 0 .
The parameters m 1 and m 2 can be expressed as function of the dimensionless
P´clet number
Pe ¼ vL=D
(see Chap. 3.5) and the dimensionless second
ohler 1 number Da 2 ¼ l L 2
Damk
=D :
1 Gerhard Damk
ohler (1908-1944), German chemist.
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