Environmental Engineering Reference
In-Depth Information
where
ν
i
is the stoichiometric coefficient of species
i
and n
i
is the number of moles of
i
.
Note that
ν
i
is negative for reactants and positive for products. For open (or continuous
flow) systems, the extent of reaction is defined as
=
φ
n
,
i
−
φ
n
,
i
0
ν
i
ξ
ð
Eq
:
6
:
6
Þ
where
φ
n
,
i
is the mole flow rate of
i
. Note that this means that the unit of
ξ
is different
for closed and for open systems! The main difference between
and
X
i
is that
conversion is dimensionless and describes how much of a certain reactant has reacted.
It is therefore dependent on the reactant considered. In contrast,
ξ
describes howmuch
the reaction has evolved and is independent of the reactant chosen for its assessment.
ξ
6.2 BATCH REACTORS (BRs)
6.2.1
Isothermal Batch Reactors
Isothermal means
constant temperature
. It is therefore a term describing those systems
in which the temperature does not change. In a batch reactor (BR), during reaction, no
reactants are supplied to the reactor and no products are released (Figure 6.1). The BR
V, c
A
X
A
, (-
R
A
)
FIGURE 6.1
Schematic of a batch reactor.
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