Environmental Engineering Reference
In-Depth Information
To calculate the evaporation constant, the Spalding mass coefficient, B M ,
which requires knowledge of the fuel mass fraction at the surface, has to be
estimated first. The Clausius
Clapeyron equation Equation (4.34) gives the
vapor mole fraction at the given droplet surface temperature, and then the
vapor mass fraction follows from Equation (4.35):
-
= exp
=0
h fg
R u =
X s = p sat
1
T boil
1
T sat
855, 000
8, 315
1
351
1
341
p atm = exp
:
6732
MW F
=
46
:
07
MW F
X s MW F +1
:
Y s =X s
MW air =0
7659
ð
X s
Þ
The Spalding mass coefficient, B M , is then evaluated fromEquation (4.39) as
B M = Y s
Y
=3
:
2718
1
Y s
Here, Y is the vapor mass fraction at infinity (i.e., far away from the drop-
let). To evaluate the evaporation constant, we need to estimate
ρ
D , which we
ðT = 800K
treat as
ρ air D
Þ
. Extrapolating the diffusivity from 273 to 800
K using
0
1
3 = 2
D T = D T 0 T
@
A
T 0
0
1
3 = 2
800
273
@
A
02 × 10 −5
m 2 s −1 =5
12 × 10 −5 m 2 s −1
=1
:
:
and using the ideal gas law to evaluate
ρ air ,
p
101, 325
8, 315
T air
m −3 =0
m −3
ρ air =
=
800 kg
:
4417 kg
ð
=
29
Þ
R u
= MW air
Thus,
K= 8
ρ air D
ρ F
ln B M +1
ð
Þ
12 × 10 −5
= 8×0
:
4417 × 5
:
328 × 10 −7 m 2
s −1
ln 3
ð
:
2718 + 1
Þ
=3
:
789
and the droplet lifetime is
2
100 × 10 −6 m
t d = d d 0
ðÞ
K
=
=0
:
030 s
K
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