Chemistry Reference
In-Depth Information
Fig. 4.10
Crystals grown from
a
Ce
3
+
-Q[6]-[CdCl
4
]
2
−
system;
b
Lu
3
+
-Q[6]-[CdCl
4
]
2
−
sys-
tem;
c
Ce
3
+
-Lu
3
+
-Q[6]-[CdCl
4
]
2
−
system; and
d
electron spectroscopy data of the stick-like
crystals from the Ce-Lu-Q[8]-[CdCl
4
]
2
−
system. Adapted from Ref. [
13
] with permission from
The Royal Society of Chemistry
crystals were first obtained (Fig.
4.10
a-c). EDS showed that the stick-like crys-
tals contained only Ce cations and no Lu (Fig.
4.10
d). Several other typical
Ln
3
+
light
−
Ln
3
heavy
−
Q[8]
−
[CdCl
4
]
2
−
systems were selected and EDS of the crystals
show high ratios
Ln
3
+
light
/
Ln
3
heavy
[
13
]. We continue to carry out further detailed
investigations aimed at developing a practically useful technique.
References
1. J.R. Long, O.M. Yaghi, Chem. Soc. Rev.
38
, 1213 (2009)
2. S.M. Cohen, Chem. Sci.
1
, 32 (2010)
3. H. Kim, Y. Kim, M. Yoon, S. Lim, S.M. Park, G. Seo, K. Kim, J. Amer. Chem. Soc.
132
,
12200 (2010)
Search WWH ::
Custom Search