Environmental Engineering Reference
In-Depth Information
Fig. 2 Proposed pathway for
peroxidases-catalyzed
degradation of 4-
(4
'
sulfophenylazo)-2,6-
dimethylphenol by
Pyricularia aryzae
(Chivukula and Renganathan
1995
)
2.2.1 Anaerobic Conditions
N=N=R
2
)+2e
−
+2H
+
(R
1
-
R
1
-
NH
NH
R
2
(Hydrazo intermediate)
→
-
-
R
2
)+2e
−
+2H
+
(R
1
-
HN
NH
R
1
-
NH
2
+R
2
-
NH
2
(Reductive cleavage of
-
-
→
the azo bond)
The exact mechanism of azo dye reduction, whether occurring intracellularly or
extracellularly,
is still a subject of investigation, as it
is the role of biogenic
intracellular water-soluble electron carriers, such as
avins. Reduced
avins can act
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