Environmental Engineering Reference
In-Depth Information
Fig. 2 Proposed pathway for
peroxidases-catalyzed
degradation of 4-
(4 ' sulfophenylazo)-2,6-
dimethylphenol by
Pyricularia aryzae
(Chivukula and Renganathan
1995 )
2.2.1 Anaerobic Conditions
N=N=R 2 )+2e +2H +
(R 1 -
R 1 -
NH
NH
R 2 (Hydrazo intermediate)
-
-
R 2 )+2e +2H +
(R 1 -
HN
NH
R 1 -
NH 2 +R 2 -
NH 2 (Reductive cleavage of
-
-
the azo bond)
The exact mechanism of azo dye reduction, whether occurring intracellularly or
extracellularly,
is still a subject of investigation, as it
is the role of biogenic
intracellular water-soluble electron carriers, such as
avins. Reduced
avins can act
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