Catalytic oxidations using ruthenium porphyrins - Advances in Catalytic Activation of Dioxygen by Metal Complexes - page 64

hydrogenations was 35 years ago; the mono- and dioxo- species, at least in a
figurative sense, correspond to the transition metal mono- and dihydrides
that began to proliferate in the 1960s. The extensive synthetic work, with
concurrent kinetic and mechanistic studies on hydrogenation of unsaturated
organics, has led in certain cases to a sophisticated understanding of the
pathways in the catalysis, such that systems have been fine-tuned for
chemo-, regio-, and enantioselective processes 110,229,230 . Corresponding
advances in catalyzed oxidation reactions are emerging and findings gleaned
from systems utilizing Ru-porphyrins will form a significant fraction of the
required data-base.

5. ABBREVIATIONS

BHT:
bromamine-T:

2,6-ditertbutyl-4-methylphenol.
N -bromo- p -toluenesulfonamide.
5,10,15-tris(4-Cl-phenyl)-20-(4-hydroxy-
pheny l)porphyrinato.
5,10,15-tris(4-Cl-phenyl)-20-(4-Merrifield
peptide resin phenyl)porphyrinato.
2,6-dichloropyridine- N -oxide.
N , N -dimethylacetamide.
N , N -dimethylformamide.
2,3,5,7,8,10,12,13,25,27,28,20-dodecaphenyl-
(porphyrinato).
hemoglobin.
histidine.
general porphyrin.
pyrazine (pyrazolato).
imidazole.
meso- 5 , 10,15,20-tetrakis(3,4,5-(trimethoxy-
phenyl)porphyrinato (and see TPP).
myoglobin.
mesoporous silicous molecular sieves.
me ta -chloroperbenzoic acid.
5-(4-carboxyphenyl)-10,15,20-triphenyl-
porphyrinato.
5,10,15-tris(4-methylphenyl)-20-(4-Merrifield
peptide resin phenyl)porphyrinato.
mesoporphyrin IX.
Merrifield's peptide resin.

DMA:
DMF:
DPP:

Hb:
hist:

Hpz (pz):
Im:
(3,4,5-MeO-TPP):

Mb:
MCM-41:
m -CPBA:
m C t PP:

MpIX:
MPR: