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identical reaction times.
Similar yields were obtained with a heterogenized cobalt catalyst
prepared by copolymerization of
[2-(acetoacetoxy)ethyl
methacrylate(
1
-)]
with
N,N -dimethylacrylamide
and
N,N' -methylenebis-
(acrylamide) 168 .
11. OXIDATIONS VIA ALKYLPEROXOCOBALT
COMPLEXES
The butylperoxocobalt(III) complex of the
pentadentate ligand N,N -bis[2-(2-pyridyl)ethyl]pyridine-2,6-dicarboxamide
Figure 59) oxidizes alkanes upon thermal decomposition 170 . The
complex can be prepared by reacting
with
in
dichloromethane.
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