Chemistry Reference
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Kinetic studies reveal first order dependence on both the catalyst
concentration and dioxygen pressure. The dependence of the initial rate on
the substrate concentration shows a saturation type behavior, indicating
reversible initial coordination of the substrate to (A), with
subsequent coordination of to the catalyst, producing intermediate
X
,
which is oxidized in the subsequent rate-determining step (Figure 48).
The proposed structure of intermediate
X
is shown in Figure 49.
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