Biomedical Engineering Reference
In-Depth Information
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Figure 12.12 Symmetric wavefunction squared
12.7 Spin
It turns out as an experimental fact that many particles have an intrinsic property called spin
just as they have a mass, a charge and so on. If the particles concerned are electrons, then
we refer to the phenomenon as electron spin . Electron spin is expressed in two possible
configurations usually referred to as spin up and spin down with respect to a given axis
of quantization. I will have more to say about electron spin in a later chapter; it does not
appear from the Schrödinger treatment, just accept it as an experimental fact for the minute.
The two states are written conventionally and and authors often use the symbol
s for the spin variable. So in the case of electrons, we might write ( s A ) to mean that
particle A was in the spin up state and ( s A ) to mean that particle A was in the spin down
state. In the case of two electrons we have four possibilities and we label the quantum
states individually ( s A ), ( s A ), ( s B ) and ( s B ). The combination ( s A )( s B ) describes
a situation where electron A has spin up and electron B has spin down and there are four
possible combination states
( s A )( s B ); ( s A )( s B );
( s A )( s B );
( s A )( s B )
 
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