Chemistry Reference
In-Depth Information
FIGURE 6.17
Fullerodendrimers with peripheral OPV units.
10
10
-10
12
s
1
). InCH
2
Cl
2
, a slightly exergonicOPV
C
60
electron transfer from the
lowest fullerene singlet level (
1
C
60
) is made possible (
!
D
G
CS
0.07 eV), but it is
observed, to an increasing extent, only in the largest systems
characterized
by a lower activation barrier for electron transfer. This effect has been related to a
40
and
41
