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FIGURE 6.5 Anion exchange reaction of [ 12 ]Br 8 with Na[ 13 ] leading to the fullerene-rich
dendrimer [ 12 ][ 13 ] 8 .
The attractive van der Waals interaction of the fullerene sphere with the planar
p
-surface of porphyrins has also been exploited to produce dendritic supramolecular
fullerene-porphyrin conjugates fromC 60 andmultiporphyrins
14
-
16
(Figure 6.6) [19].
FIGURE 6.6
Dendrimers 14 - 16 with peripheral porphyrin subunits.
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