Chemistry Reference
In-Depth Information
FIGURE 6.5
Anion exchange reaction of [
12
]Br
8
with Na[
13
] leading to the fullerene-rich
dendrimer [
12
][
13
]
8
.
The attractive van der Waals interaction of the fullerene sphere with the planar
p
-surface of porphyrins has also been exploited to produce dendritic supramolecular
fullerene-porphyrin conjugates fromC
60
andmultiporphyrins
14
-
16
(Figure 6.6) [19].
FIGURE 6.6
Dendrimers
14
-
16
with peripheral porphyrin subunits.