Chemistry Reference
In-Depth Information
SCHEME 5.24
Time-consuming desymmetrization leading to
80
and
81
.
The ester group enables interfacial anchoring on functionalized surfaces, particles,
or biologically active moieties with the perylenetetracarboxydiimides possessing
fluorescence quantum yields near unity serving as highly emitting sensors.
Another asymmetric dendrimer with a Ru-core was achieved starting from the
dichlororuthenium derivative
(Scheme 5.27). It was synthesized and coupled
with the second-generation bipyridine dendron
85
85
in order to establish the macro-
molecule
86
[55].
SCHEME 5.25
One-step synthesis of desymmetrized core
82
.
