Chemistry Reference
In-Depth Information
Table 2.1 Relative transamination rates at pH 4.0 in methanol with
Zn(OAc)
2
of small pyridoxamine analogs incorporating basic side arms.
Compound
R
k
rel
1
SCH
2
CH
2
CH
3
1.00
2
OH
1.4
3
NMe
2
14
4
SCH
2
CH
2
NMe
2
26
5
SCH
2
CH
2
CH
2
NMe
2
37
6
SCH
2
CH
2
CH
2
CH
2
NMe
2
13
7
5.6
8
12
9
76
10
26
11
11
12
27
13
110
14
87
15
200
