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N
N
O
O
10
10
Br
N
N
Br 570 GM
1200 GM
4-(2-(7-(2-(4-(dimethylamino)phenyl)ethynyl)-9,9-bis(2-methoxyethyl)-9 H -uoren-2-yl)ethynyl)- N,N
-dimethylbenzenamine
4-(2-(2,5-dibromo-4-(2-(4-(dihexylamino)phenyl)ethynyl)phenyl)ethynyl)- N,N
-dihexylbenzenamine
C 10 H 21
C 10 H 21
O
CN
Ph 2 N
N
S
N
O
H 3 C
2
N
NC
H
H
600 GM
2517 GM
(E)-2-(4-(4-(pyridin-2-ylmethyl)piperazin-1-yl)styryl)-5-methylterephthalonitrile
N -(4-(2-(7-(4-(phenylsulfonyl)phenethyl)-9,9-didecyl-9H-uoren-2-yl)ethyl)phenyl)- N
-phenylbenzenamine
400
N
N
Lasing
C 10 H 21
300
S
C 10 H 21
S
S
S
200
Fluor×100
Superuor×10
100
900 GM
0
400
500
600
2,2?-(5,5?-(9,9-didecyl-9H-uorene-2,7-diyl)bis(ethyne-2,1-diyl)bis(thiophene-5,2-diyl))
-dibenzo[d]-thiazole
Wavelength, nm
fIgure 11.33 Structures of five fluorescence compounds available for in vitro imaging with two-photon absorption cross section greater than 500 GM and
one example of the superfluorescence properties of 2,2′-(5,5′-(9,9-didecyl-9H-fluorene-2,7-diyl)bis(ethyne-2,1-diyl)bis(thiophene-5,2-diyl))-dibenzo[d]-thia-
zole with their two-photon induced green emission in vitro [139-143].
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