Chemistry Reference
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chelation technique may be applied to recycle rare metals from used goods. Organosu-
perbases with strong basicity could be potential candidates for these purposes.
As discussed in Chapter 4 (Oxazolidinone and Oxazole), guanidines catalyze the
insertion of carbon dioxide (CO 2 ) to alkynic bonds [22]. This behaviour may give a hint
to trapping CO 2 by organobase catalyzed chemical reaction, even to necessarymodification
of reaction conditions. Hopefully, it is the ideal that the CO 2 -incorporated products could be
used as new energy sources.
References
1. For example: Anestas, P.T. and Warner, J.C. (1998) Green Chemistry: Theory and Practice,
Oxford University Press, Oxford.
2. For example: Shibuguchi, T., Fukuta, Y., Akachi, Y. et al. (2002) Development of new
asymmetric two-center catalysts in phase-transfer reactions. Tetrahedron Letters, 45, 9539-9543.
Ohshima, T., Shibuguchi, T., Fukuta, Y. and Shibasaki, M. (2004) Catalytic asymmetric phase-
transfer reactions using tartarate-derived asymmetric two-center organocatalysts. Tetrahedron,
60, 7743-7754.
3. For example: Atwood, J.L., Davies, J.E. and MacNicol, D.D. (1984) Inclusion Compounds,3,
Academic Press, New York.
4. For example: Walters, W.P., Stahl, M.T. and Murcko, M.A. (1998) Virtual screening - an
overview. Drug Discovery Today, 3, 160-178.
5. Kovacevic, B. and Maksic, Z.B. (1998) Toward engineering of very strong organic bases:
pronounced proton affinity of molecules possessing imino structural and electronic motif.
Chemical Physics Letters, 288, 289-292.
6. Maksic, Z.B. and Kovacevic, B. (1999) Spatial and electronic structure of highly basic organic
molecules: cyclopropeneimines and some related systems. Journal of Physical Chemistry A, 103,
6678-6684.
7. Gattin, Z., Kovacevic, B. and Maksic, Z.B. (2005) Cooperative intramolecular hydrogen
bonding effect and basicity - an ab initio and DFT study of the superbasic properties of N-
[(dimethylamino)alkyl]-2,3-diaminocycloprop-2-ene-1-imines. European Journal of Organic
Chemistry, 3206-3213.
8. Maksic, Z.B. and Kovacevic, B. (1998) Toward organic superbases: the electronic structure and
the absolute proton affinity of quinodiimines and some related compounds. Journal of Physical
Chemistry A, 102, 7324-7328.
9. Despotovic, I., Maksic, Z.B. and Vianello, R. (2007) Design of Brønsted neutral organic bases
and superbases by computational DFT methods: cyclic and polycyclic quinones and [3]
carbonylradialenes. European Journal of Organic Chemistry, 3402-3413.
10. Despotovic, I., Maksic, Z.B. and Vianello, R. (2006) Engineering neutral organic bases and
superbases by computational DFT methods - carbonyl polyenes. European Journal of Organic
Chemistry, 5505-5514.
11. Vianello, R., Kovaevic, B. and Maksic, Z.B. (2002) In search of neutral organic superbases -
iminopolyenes and their amino derivatives. New Journal of Chemistry, 26, 1324-1328.
12. Despotovic, I., Maksic, Z.B. and Vianello, R. (2007) Computational design of Brønsted neutral
organic superbases-[3]iminoradialenes and quinoimines are important synthetic targets. New
Journal of Chemistry, 31, 52-62.
13. Maksic, Z.B., Glasovac, Z. and Despotovic, I. (2002) Predicted high proton affinity of poly-2,5-
dihydropyrrolimines - the aromatic domino effect. Journal of Physical Organic Chemistry, 15,
499-508.
14. Despotovic, I., Kovacevic, B. and Maksic, Z.B. (2007) Pyridine and s-triazine as building blocks
of nonionic organic superbases - density functional theory B3LYP study. New Journal of
Chemistry, 31, 447-457.
 
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