Chemistry Reference
In-Depth Information
The electrophile, NO 2 + , is formed as in eq. 4.18. Then the mechanism follows
the same steps as the solution to Example 4.2.
4.30
a.
+
NO 2
H
N 2
H
N 2
H
N
2
H 3
C
H 3
C
H 3
C
H 3
C
+
+
CH 3
CH 3
+
CH 3
CH 3
NO 2
H 3
C
+H +
CH 3
b.
The electrophile is formed as in eq. 4.20:
AlCl 4 _
+
(CH 3 ) 3 C
(CH 3 ) 3 CCl
+
AlCl 3
+
Then
+
(
CH
33
H
C
(
CH
33
H
C
(
CH
33
H
C
(
CH
33
+
+
+
CH 3
CH 3
CH 3
CH 3
C
(
CH
33
+H +
CH 3
 
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